Ph diagram for nitrogen. By employing a mean field model calculation of the tp phase diagram of molecular nitrogen is performed at high pressures up to 200 gpa. Pourbaix diagrams are also known as e h ph diagrams due to the labeling of the two axesthe vertical axis is labeled e h for the voltage potential with respect to the standard hydrogen electrode she as calculated by the nernst equationthe h stands for hydrogen although other standards may be used and they are for room temperature only. Systems appendix glossary the pressure enthalpy diagram log ph diagram is a very useful tool for refrigerant technicians. Adapted from canjar ln.
R o reduc oxid n pe pe log 1 0 k n pe log 1 0 oxidizing limit. Data source japannuclear cycleorganization. The thermodynamic data for important nitrogen species are given in table 7. Pourbaix diagram for nitrogen.
This w3c unspecified vector image was created with inkscape. Pressureenthalpy diagrams for various compounds. Top diagram shows potentials at ph 0. Frost diagram for nitrogen at different ph levels the ph dependence is given by the factor 0059 m n per ph unit where m relates to the number of protons in the equation and n the number of electrons exchanged.
Permission i the copyright holder of this work hereby publish it under the following license. Bottom diagram shows potentials at ph 14. Experimental data from the literature are used to fit a quadratic function in t and p describing the phase line equations which have been derived using the mean field model studied here for n2 and the fitted parameters are determined. The diagram shows that a mixed oxide fecrc is stable under the reducing conditions imposed by hydrogen water chemistry hwc for bwr while the simple oxide feo is stable for the more oxidizing conditions of normal water chemistry.
24 the complex cycle in a log ph diagram. Nitrogen n3 was the important gaseous form during hydrogen injection into bwr feedwater. Electrons are always exchanged in electrochemistry but not necessarily protons. The eh ph diagram for nitrogen species is shown in fig.
Pe ph diagrams pe ph stability field diagramsshow in a comprehensive way how protons ph and electrons pe simultaneously shift equilibria of reactions under various conditions these diagrams also indicate which species predominate under any given condition of pe and ph two equations are used to produce the diagrams. Keywords physical chemistry nitric oxide equilibrium condition thermodynamic data nitrogen species these keywords were added by machine and not by the authors. This file is licensed under the creative commons attribution share. With permission figure d2 nitrogen pressureenthalpy diagram.
The presence of cr in the oxide may account. Figure d1 oxygen pressureenthalpy diagram. First an explanation of how the diagram is built up is given and then its use is. This process is experimental and the keywords may be updated as the learning algorithm improves.
Cn 10 10 moll t 25 0c.